Anders Palmqvist - Chalmers Research

Adrian Rennie - Uppsala universitet

1.5 g of dry as-synthesized material was dissolved in a mixture of HCl (20 mL) and EtOH (205 mL), the resultant mixture was refluxed at 70 °C for 24 h. The oxidation process is the same as described above. Sulfonic acid-functionalized mesostructured silicas have demonstrated excellent catalytic behaviour in the acetalisation of glycerol with acetone to yield 2,2-dimethyl-1,3-dioxolane-4-methanol, also known as solketal. This molecule constitutes an excellent compound for the formulation of gasoline, diesel and biodiesel fuels. Sulfonic-acid-functionalized mesostructured silicas have demonstrated an excellent catalytic behavior in the etherification of glycerol with isobutylene to yield tert-butylated derivates. Di- tert -butylglycerols (DTBG) and tri- tert -butylglycerol (TTBG) have shown to be valuable fuel additives leading to decreases in the emission of Catalyst performance of the acid-functionalized mesoporous catalyst materials typi- cally show weight loss profiles that can be divided into three Propyl- and arene-sulfonic acid modified mesostructured regions: (1) from room temperature to 150 C attributed to SBA-15 silicas have previously been demonstrated as active water desorption, (2 Textural properties of sulfonic acid-modified mesostructured silicas have been evaluated by means of nitrogen adsorption and desorption isotherm at 77 K using a Micromeritics TRISTAR 3000 system. ata were analyzed using the BJH model and D pore volume was taken at P/Po= 0.975 single point.

In this case, following the prehydrolysis step of the The onset temperatures for thermal decomposition of the different sulfonic acid moieties considered in this study, although obtained in a thermally- controlled oven under a 5ºC·min-1 temperature ramp and not under the transesterification reaction conditions, suppose a valid indication of the high thermal stability of the sulfonic acid sites incorporated onto the SBA-15 mesostructured silicas. Sulfonic acid-functionalized mesostructured silicas have demonstrated excellent catalytic behaviour in the acetalisation of glycerol with acetone to yield 2,2-dimethyl-1,3-dioxolane-4-methanol Supported and Free‐Standing Sulfonic Acid Functionalized Mesostructured Silica Films with High Proton Conductivity DOI: 10.1016/J.APCATA.2008.04.041 Corpus ID: 53598576. Acid-catalyzed etherification of bio-glycerol and isobutylene over sulfonic mesostructured silicas @article{Melero2008AcidcatalyzedEO, title={Acid-catalyzed etherification of bio-glycerol and isobutylene over sulfonic mesostructured silicas}, author={J. Melero and G. Vicente and Gabriel Morales and M. Paniagua and J. M. Moreno and R. Rold By subsequent chemical derivatization of the grafted species, thiol and sulfonic acid modified silicas are obtained.

Sveriges lantbruksuniversitet - Primo - SLU-biblioteket

2013-09-10 · Sulfonic mesoporous silicas have demonstrated an outstanding catalytic performance in the esterification of levulinic acid with different alcohols to produce alkyl levulinates, a family of chemicals considered to be excellent oxygenated fuel extenders for gasoline, diesel and biodiesel. Samples were heated in a Mettler TGA/sDTA- Propyl-sulfonic-acid functionalized mesostructured silica 851e ThermoGravimetric Analyzer from 25 to 800 C at a rate and organosilica were synthesized following a one-pot co- of 10 C/min under constant nitrogen gas flow of 50 ml/min. condensation procedure previously employed for the prepara- The concentrations of surface sulfonic acid groups were deter- tion of propyl-sulfonic-acid functionalized silica SBA-15 [11]. Efficient conversion of levulinic acid into alkyl levulinates catalyzed by sulfonic mesostructured silicas .

PDF Polyvinyl chloride-hyperbranched polyamidoamine

Physica. 6 dec. 2015 — Figur 2.

CAS Article Google Scholar Línea Investigación: Línea 8. Producción de biocombustibles. Show simple item record. Efficient conversion of levulinic acid into alkyl levulinates catalyzed by sulfonic mesostructured silicas Likewise, the use of mesostructured supports has been shown as a factor improving the catalytic performance as compared with macroporous sulfonic acid-based resins, likely due to an enhancement of the mass transfer rates of large molecules, such as triglycerides, within the catalyst structure. ion-exchange resins, sulfonic acid mesostructured silicas, sulfonated carbons, heteropolyacids, sulfated zirconia and acidic ionic liquids have been studied for The formation of lamellar mesostructured silica by a neutral route in dodecylbenzene sulfonic acid (DBSA)/aminoalkoxysilane/water systems was investigated by Sulfonic acid-functionalized mesostructured silicas have demonstrated excellent SBA-15 mesoporous silica has been functionalized with arenesulfonic acid SBA-15 mesostructured silica functionalized with sulfonic acids was evaluated as sorbent.
Timmermans garden

2015 — Figur 2. Fastställande av mesostructured kristallgitter och ytparametrar av vagnhjulformade porer. N-cyclohexyl-3-aminopropane sulfonic acid (CAPS), Dojindo El-Safty, S. A. Functionalized hexagonal mesoporous silica av C De la Torre Paredes · 2018 — mesoporous silica nanoparticles using peptides as molecular gates in which the release of the tetraacetic acid, chloride, urea or sulfonic acid groups, the materials proved to be [45] Calcination of the mesostructured phase resulted in the. additiveson the morphology of mesostructured silica templated by pluronics. opening reaction using oleic acid (OA) with p-toluene sulfonic acid (PTSA) as a Substitution of Nafion with sulfonated polysulfone in membrane–electrode Silica fluxes and trapping in two contrasting natural impoundments of the upper of cohesive fatigue effects in grain boundaries of a piezoelectric mesostructure (APS) allowing for covalent binding to the calcined mesostructured silica. by thiol-modified MCM, or oxidation of the thiol to sulfonic acid groups [82].

This molecule constitutes an excellent compound for the formulation of gasoline, diesel and biodiesel fuels. Sulfonic-acid-functionalized mesostructured silicas have demonstrated an excellent catalytic behavior in the etherification of glycerol with isobutylene to yield tert-butylated derivates. Di- tert -butylglycerols (DTBG) and tri- tert -butylglycerol (TTBG) have shown to be valuable fuel additives leading to decreases in the emission of Catalyst performance of the acid-functionalized mesoporous catalyst materials typi- cally show weight loss profiles that can be divided into three Propyl- and arene-sulfonic acid modified mesostructured regions: (1) from room temperature to 150 C attributed to SBA-15 silicas have previously been demonstrated as active water desorption, (2 Textural properties of sulfonic acid-modified mesostructured silicas have been evaluated by means of nitrogen adsorption and desorption isotherm at 77 K using a Micromeritics TRISTAR 3000 system. ata were analyzed using the BJH model and D pore volume was taken at P/Po= 0.975 single point. Structural characterization was Sulfonic mesoporous silicas have demonstrated an outstanding catalytic performance in the esterification of levulinic acid with different alcohols to produce alkyl levulinates, a family of chemicals considered to be excellent oxygenated fuel extenders for gasoline, diesel and biodiesel. sulfonic acid-modified mesostructured silicas provide different acid strengths, as introduced by the different molecular environments of the sulfonic acid sites (Pr-SO 3 Textural properties of sulfonic acid-modified mesostructured silicas have been assessed by means of nitrogen adsorption and desorption isotherm at 77 K using a Micromeritics TRISTAR 3000 system. Pores sizes distributions were calculated using the BJH method using the KJS correction, and total pore volume was taken at P/Po = 0.975 single point.
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The activity achieved with arenesulfonic acid-functionalized silica of this work was to evaluate sulfonic acid-functionalized SBA-15 mesostructured silicas as strong cation-exchange (SCX) SPE sorbents for the analysis of TAs in GF matrices by HPLC-MS/MS. As atropine and scopolamine are the most prevalent TAs in this kind of samples, they were chosen as target analytes. Sulfonated mesostructured silica-carbon nanocomposites with varying carbon content, acidic site density and porosity, obtained via the one-pot evaporation induced self-assembly (EISA) synthesis The unique properties of mesostructured cellular foam (MCF) silica such as, large pore size, continuous three-dimensional (3D) pore system and hydrothermal robust materialallow favorable conditions for incorporating active sites to produce modified MCF silica as catalysts, biocatalysts and adsorbents. Recently, the modified MCF silicas were reported to be efficient catalysts for the Sulfonic-acid functionalized mesostructured silicas have demonstrated an excellent catalytic behavior in the etherification of glycerol with isobutylene to yield tert-butylated derivates. Mesoporous silica materials (HS-JLU-20) with an extremely high content of mercaptopropyl groups have been successfully synthesized using fluorocarbon−hydrocarbon surfactant mixtures through a simple co-condensation approach of tetraethyl orthosilicate (TEOS) and (3-mercaptopropyl)trimethoxysilane (MPTS), which are characterized by X-ray diffraction (XRD), nitrogen adsorption and desorption 10% of total silicon atoms were functionalized with propyl-sulfonic acid groups. Arene-sulfonic-acid functionalized mesostructured silica and organosilica were synthesized simily to that described for the lar -sulfonic-acid functionalized propyl mesoporous solids above [13]. In this case, following the prehydrolysis step of the The onset temperatures for thermal decomposition of the different sulfonic acid moieties considered in this study, although obtained in a thermally- controlled oven under a 5ºC·min-1 temperature ramp and not under the transesterification reaction conditions, suppose a valid indication of the high thermal stability of the sulfonic acid sites incorporated onto the SBA-15 mesostructured silicas.

Morales G, Paniagua M, Melero JA, 1.1.2 Periodic mesoporous silicas: synthesis and mechanisms . Perfluorinated sulfonic acid sultone grafting on mesostructured silica materials. I. F. F F. F. Nov 13, 2019 They were used to incorporate active sites as in propyl sulfonic acid, sulphated metal oxides, platinum and nickel [3, 4, 5, 6, 7, 8, 9, 10]. The Jul 31, 2020 The distribution of organic carbon precursors in mesostructured silica is a vibration of the sulfonic acid group grafted on the carbon surface. 6 days ago Sulfonic acid-functionalized mesostructured silicas have been evaluated in the solvent-free aldol dimerization of biomass-derived levulinic acid Oct 12, 2016 Silica supported sulfonic acid catalysts operate under mild conditions and Melero described the synthesis of mesostructured silica frame-. Jun 21, 2012 After calcination, silicas were functionalized with sulfonic acid groups by 2D, 3D mesostructured silicas templated mesoporous manganese Sep 25, 2015 Mono-dispersed spherical particles of mesoporous silicas with the particle The introduction of guest species into mesostructured materials will be Such acidic functionalities as imidazole [195], sulfonic acid [194 Aluminosilicate, mesostructured (Al-MSU) is an analog of hexagonal MCM-41 that can be assembled Silica, mesostructured SBA-15, 99% trace metals basis. The etherification of glycerol with benzyl alcohol was carried out over mesostructured silica, SBA‐15, with sulfonic acid groups.
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Molecular design of the surfactant and the co-structure - DiVA

A series of mercaptopropyl-functionalized wormhole mesostructures, denoted MP-HMS, have been prepared through the S0I0 assembly of alkylamine surfactants (S0) and mixtures of 3-mercaptopropyltrimethoxysilane and tetraethyl orthosilicate as framework precursors (I0). Unprecedented levels of organo functionalization, corresponding to at least 50% of the silicon sites, were achieved while review recent advances in catalytic applications of sulfonic acid-based mesostructures in a comprehensive paper. Primary reports on sulfonic acid-based precursors go back to 1998 [8-10], in which the earliest versions of SAPs in mesoporous silicas were prepared by two general routes: 1) post-functionalization of mesoporous silica with 3- Sulfonic acid-functionalized mesostructured SBA-15 silicas have been demonstrated to be active for the catalytic transesterification of glycerol with methyl acetate to produce di- and triacetylglycerols. An optimization of the reaction conditions carried out with pharmaceutical glycerol by means of experimental design methodology showed that it is necessary to use a high methyl acetate to Catalyst performance of the acid-functionalized mesoporous catalyst materials typi- cally show weight loss profiles that can be divided into three Propyl- and arene-sulfonic acid modified mesostructured regions: (1) from room temperature to 150 C attributed to SBA-15 silicas have previously been demonstrated as active water desorption, (2 Sulfonic mesoporous silicas have demonstrated an outstanding catalytic performance in the esterification of levulinic acid with different alcohols to produce alkyl levulinates, a family of chemicals considered to be excellent oxygenated fuel extenders for gasoline, diesel and biodiesel. Sulfonic acid functionalized silica films with 2D‐hexagonal mesostructures of various channel sizes are prepared in a one‐step synthesis. A successful combination of in situ oxidation of a mercapto‐functionalized silane with an evaporation induced self‐assembly (EISA) process in the presence of amphiphilic block copolymers allows the formation of a highly structured material with a Textural properties of sulfonic acid-modified mesostructured silicas have been assessed by means of nitrogen adsorption and desorption isotherm at 77 K using a Micromeritics TRISTAR 3000 system. Pores sizes distributions were calculated using the BJH method using the KJS correction, and total pore volume was taken at P/Po = 0.975 single point.